A Divergent Synthetic Route to the Vallesamidine and Schizozygine Alkaloids: Total Synthesis of (+)‐Vallesamidine and (+)‐14,15‐Dehydrostrempeliopine
Author:
Affiliation:
1. Department of ChemistryUniversity College London 20 Gordon Street London WC1H 0AJ UK
Funder
China Scholarship Council
University College London
Publisher
Wiley
Subject
General Medicine
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.201910593
Reference109 articles.
1. Alkaloid-Studien LII. Die Alkaloide ausVallesia dichotoma RUIZet PAV
2. Alkaloids from Roots ofStrempeliopsis strempelioides- Structures of Strempeliopine and Strempeliopidine
3. Ethnobotany of Apocynaceae species in Kenya
4. Although no synthesis of schizozygine (3) has been reported the structurally rearranged analogue isoschizogamine has received more attention and several total syntheses have been completed; see:
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1. BF 3 Mediated [1,5]‐Hydride Shift Triggered Cyclization: Thioethers Join the Game;European Journal of Organic Chemistry;2022-07
2. Metathesis Reactions in Natural Product Fragments and Total Syntheses;Asian Journal of Organic Chemistry;2022-02-23
3. Asymmetric Total Syntheses of Schizozygane Alkaloids;Journal of the American Chemical Society;2021-11-19
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