Transition‐Metal‐Catalyzed Cyclization of Alkenyl Iodide

Author:

Jia Yuwei1,Liu Qing1ORCID,Xie Caixia1,Li Xiaowei1,Liu Hui1

Affiliation:

1. School of Chemistry and Chemical Engineering Shandong University of Technology 266 West Xincun Road Zibo 255049 People's Republic of China

Abstract

AbstractAlkenyl iodide, as an essential precursor and structural unit in organic synthesis, has been widely used in the synthesis of natural products, pharmaceutical pesticides and functional materials. The high reactivity of the Csp2−I bond enables the formation of a C−M bond through oxidative addition, followed by subsequent transformations of the C−M bond to create new chemical bonds. A variety of valuable scaffolds, in particular the cyclic motifs, could be achieved via designing and synthesis the corresponding alkenyl iodide, which makes this strategy to be a hot topic in synthetic chemistry. In this paper, the recent progresses of transition metal‐catalyzed cyclizationof alkenyl iodides are summarized, and the possible mechanisms for most transformations are described in detail.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry

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