Affiliation:
1. Chongqing Key Laboratory of Natural Product Synthesis and Drug Research School of Pharmaceutical Sciences Chongqing University Chongqing 401331 People's Republic of China
2. State Key Laboratory of Chemical Oncogenomics Key Laboratory of Chemical Genomics Peking University Shenzhen Graduate School Shenzhen 518055 Guangdong People's Republic of China
Abstract
AbstractThe first iron‐catalyzed oxophosphorylation of styrene derivatives with dialkyl H‐phosphonates under open air conditions is developed, which generates a range of previously underexplored α‐substituted β‐ketophosphonates in 55~70% yields. Furthermore, a convenient one‐pot procedure by direct conversion of styrenes to α, β‐unsaturated ketones is also developed based on the new catalytic reactions, thus offering a protocol to access two classes of valuable products from simple starting materials.
Funder
Natural Science Foundation of Chongqing Municipality
Subject
Organic Chemistry,Catalysis
Cited by
2 articles.
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