Affiliation:
1. Henan Key Laboratory of Chemical Biology and Organic Chemistry College of Chemistry Zhengzhou University Zhengzhou 450001 People's Republic of China
2. Pingyuan Laboratory Zhengzhou University) Zhengzhou 450001 People's Republic of China
Abstract
AbstractThe catalytic asymmetric dearomative arylation of 2‐naphthols enabled by the unconventional reactivity of o‐quinone diimides, i. e. the 1,4‐conjugate addition on quinone sp2 hybridized carbon, has been established. Under the catalysis of chiral phosphoric acid, various cyclohexaenones bearing an all‐carbon quaternary stereocenter have been prepared with excellent yields and enantioselectivities.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Henan Province