Electrochemical Oxidative C−C Bond Functionalization of Methylenecyclopropanes with Diselenides/Ditellurides Leading to 2‐Substituted‐3,4‐Dihydronaphthalenes-Reference-Cited by-同舟云学术

Electrochemical Oxidative C−C Bond Functionalization of Methylenecyclopropanes with Diselenides/Ditellurides Leading to 2‐Substituted‐3,4‐Dihydronaphthalenes

Published:2023-08-31 Issue:19 Volume:365 Page:3295-3300
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Zhan Lei¹,Gao Lei¹,Pan Ying‐Ming²^ORCID,He Mu‐Xue¹³^ORCID,Ma Xian‐Li¹,Mo Zu‐Yu¹³^ORCID

Affiliation:

1. Guangxi Key Laboratory of Drug Discovery and Optimization Guangxi Engineering Research Center for Pharmaceutical Molecular Screening and Druggability Evaluation Pharmacy School of Guilin Medical University Guilin 541199 People's Republic of China

2. State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources School of Chemistry and Pharmaceutical Sciences of Guangxi Normal University Guilin 541004 People's Republic of China

3. Key Laboratory of Agricultural Resources Chemistry and Biotechnology College of Chemistry and Food Science of Yulin Normal University Yulin 537000 People's Republic of China

Abstract

AbstractThis study presents an approach for the electrochemical oxidation ring‐opening/cyclization reaction of methylcyclopropane with diselenides/ditellurides, leading to the synthesis of diverse 2‐substituted‐3,4‐dihydronaphthalene derivatives with exceptional selectivity and efficiency. This methodology involves C(sp3)−H functionalization, ring opening and cyclization processes. One characteristic of this method is its ability to accommodate a wide range of substrates with various functional groups.

Funder

Natural Science Foundation of Guangxi Zhuang Autonomous Region

Publisher

Wiley

Subject

Organic Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202300730

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