Affiliation:
1. State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources School of Chemistry and Pharmaceutical Sciences of Guangxi Normal University Guilin 541004 People's Republic of China
Abstract
AbstractIn the presence of the Suginome reagent (PhMe2Si−Bpin), a large panel of electron‐withdrawing alkenes was successfully converted into the hydrosilylated product in good to excellent yields. This direct electrochemical hydrosilylation does not require exogenous oxidants and catalysts. Preliminary mechanistic study supported the involvement of a silyl radical, which reacted on the alkene.magnified image
Funder
National Natural Science Foundation of China
Cited by
4 articles.
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