Application of Sulfoxonium Ylides or Iodonium Ylides in Rhodium‐Catalyzed Synthesis of Phenanthrenes-Reference-Cited by-同舟云学术

Application of Sulfoxonium Ylides or Iodonium Ylides in Rhodium‐Catalyzed Synthesis of Phenanthrenes

Published:2024-03-07 Issue:8 Volume:366 Page:1744-1750
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Liu Xiao¹,Zhou Bingxin¹,Yan Kelu¹^ORCID,Wen Jiangwei¹^ORCID,Li Qiuyun²,Wang Xutong¹,Wang Xiu¹

Affiliation:

1. Key Laboratory of Life-Organic Analysis of Shandong Province School of Chemistry and Chemical Engineering Qufu Normal University Qufu 273165 People's Republic of China

2. Faculty of Chemistry and Chemical Engineering Yancheng Institute of Technology Yancheng 224051 People's Republic of China

Abstract

AbstractThe transmetalation triggered rhodium‐catalyzed C−H bond activation and tandem annulation of 2‐biphenylboronic acids with sulfoxonium ylides or iodonium ylides has been developed. Various products of phenanthrenes were constructed under redox‐neutral conditions in 34–86% yields. Several mechanism exploration experiments and derivatization reactions were conducted in sequence to gain a deeper understanding of the process and the potential of this transformation. It offers an alternative approach for the synthesis of phenanthrene derivatives.

Funder

National Natural Science Foundation of China

Qufu Normal University

Yancheng Institute of Technology

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202301451

Reference98 articles.

1. For Selected Recent Reviews on Transition-Metal-Catalyzed C−H Activation See:

2. Palladium-Catalyzed Transformations of Alkyl C–H Bonds

3. Oxidative C–H/C–H Coupling Reactions between Two (Hetero)arenes

4. 3d Transition Metals for C–H Activation

5. Bidentate Directing Groups: An Efficient Tool in C–H Bond Functionalization Chemistry for the Expedient Construction of C–C Bonds

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