Affiliation:
1. School of Chemistry Indian Institute of Science Education and Research Thiruvananthapuram Vithura Thiruvananthapuram Kerala 695551 India
Abstract
AbstractSilylzinc reagents are desirable for the synthesis of organosilanes due to their compatibility with functional groups; however, the use of pyrophoric silyllithium and dissolved lithium salts in their production hinders their development. Our solid Me3SiZnI circumvents these limitations, and herein, we demonstrate its significance in the synthesis of aryl and alkyl trimethylsilanes via cross‐coupling of aryl and alkyl bromides. The milder reaction condition tolerates functional groups such as MOM, Boc, Bpin, and aldehydes.
Funder
Science and Engineering Research Board
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