Designing Donor‐Acceptor Cyclopropane for the ThermalSynthesis of Carbocyclic Eight‐Membered Rings-Reference-Cited by-同舟云学术

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Designing Donor‐Acceptor Cyclopropane for the ThermalSynthesis of Carbocyclic Eight‐Membered Rings

Published:2023-03-24 Issue:7 Volume:365 Page:1002-1011
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Masson Kévin¹,Dousset Maxime¹,Biletskyi Bohdan¹,Chentouf Sara²,Naubron Jean‐Valère²,Parrain Jean‐Luc¹^ORCID,Commeiras Laurent¹^ORCID,Nava Paola¹^ORCID,Chouraqui Gaëlle¹^ORCID

Affiliation:

1. Aix Marseille Univ, CNRS Centrale Marseille iSm2 Marseille France

2. Aix Marseille Univ, CNRS Centrale Marseille Spectropole FR1739 Marseille France

Abstract

AbstractAn access to functionalised eight‐membered carbocyclic ring compounds was developed by simply stirring an unusual vinylogous Donor‐Acceptor Cyclopropane (DAC) in boilingo‐xylene. Both experimental and computational studies were performed to explain the diastereoselectivity/regioselectivity transfer observed and to provide an overall picture of the mechanism.

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Publisher

Wiley

Subject

General Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202300015

Reference126 articles.

2. The synthesis of carbocyclic eight-membered rings

3. Progress in the Construction of Cyclooctanoid Systems: New Approaches and Applications to Natural Product Syntheses

4. Synthesis of Medium-Sized Rings by the Ring-Closing Metathesis Reaction

5. Synthese von mittleren Ringen durch Ringschluss-Metathese-Reaktion

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