Nickel/Copper Co‐catalyzed Enantioselective Reductive Coupling of Oxabenzonorbornadienes with Vinyl Bromides-Reference-Cited by-同舟云学术

Nickel/Copper Co‐catalyzed Enantioselective Reductive Coupling of Oxabenzonorbornadienes with Vinyl Bromides

Published:2023-08-29 Issue:19 Volume:365 Page:3265-3270
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Deng Yao¹,Meng Yunyan¹,Yang Qiongtong¹,Liu Zixiu¹,Fan Ruifeng¹,Chen Jingchao¹,Fan Baomin¹²³^ORCID

Affiliation:

1. Key Laboratory of Chemistry in Ethnic Medicinal Resources (Yunnan Minzu University) State Ethnic Affairs Commission & Ministry of Education Yunnan Minzu University 650504 Kunming Yunnan People's Republic of China

2. Department School of Chemistry and Environment Yunnan Minzu University 650504 Kunming Yunnan People's Republic of China

3. School of Pharmaceutical Science & Yunnan Key Laboratory of Pharmacology for Natural Products Kunming Medical University Kunming Yunnan 650500 People's Republic of China

Abstract

AbstractThe enantioselective reductive coupling of oxabenzonorbornadiene with vinyl bromide is developed with earth‐abundant nickel catalyst with copper as Lewis acid co‐catalyst. The asymmetric reductive coupling is applicable with a wide range of azabenzonorbornadienes and vinyl bromides under nickel/copper co‐catalytic system, affording the cis ring‐opening vinylation products in good yields with high optical purities. The present study has enabled straightforward stereoselective preparation of chiral 2‐vinyl‐tetrahydronaphthalens from vinyl halides.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Organic Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202300633

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