Selective Hydro‐ and Deuterodechlorination of Trichloroacetamides under Controlled Electrochemical Conditions To Prepare Mono‐, Di‐, and Deuterochloroacetamides-Reference-Cited by-同舟云学术

Selective Hydro‐ and Deuterodechlorination of Trichloroacetamides under Controlled Electrochemical Conditions To Prepare Mono‐, Di‐, and Deuterochloroacetamides

Published:2024-05-29 Issue:12 Volume:366 Page:2696-2704
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Bandyopadhyay Manas¹^ORCID,Bera Biman¹,Pathak Swastik¹,Bhunia Dipendu¹,Bhadra Sayan¹,Patra Snehangshu²,Pal Chowdhury Manish³,Escorihuela Jorge⁴^ORCID,Bera Mrinal K.¹^ORCID

Affiliation:

1. Department of Chemistry Indian Institute of Engineering Science and Technology (IIEST) Shibpur, P O Botanic Garden Howrah 711103 WB India

2. Sustainable Hydrogen for Valuable Applications (SHYVA) 23 Allee Gilbert Becaud 34470 Perols France

3. Department of Physics Indian Institute of Engineering Science and Technology (IIEST) Shibpur, P O Botanic Garden Howrah 711103 WB India

4. Departamento de Química Orgánica, Universitat de València Avda. Vicente Andrés Estellés s/n, Burjassot 46100 Valencia Spain

Abstract

AbstractMono‐ and dichloro acetamides were prepared via a hydrodechlorination reaction of trichloroacetamides under controlled electrochemical conditions. The reactions were carried out in an undivided cell with constant current flow using n‐Bu4NI as supporting electrolyte and methanol as solvent and proton source. Deuterodechlorination of trichloroacetamide was also successful when methanol‐d4 was used as solvent under identical electrochemical conditions.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202400372

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