Enantioselective Reduction of Cyclobutenones Using Ene‐Reductases-Reference-Cited by-同舟云学术

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Enantioselective Reduction of Cyclobutenones Using Ene‐Reductases

Published:2024-07-17 Issue:15 Volume:366 Page:3257-3261
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Yasukawa Tomohiro¹,Gilles Pierre²,Martin Juliette²,Boutet Julien³,Cossy Janine¹^ORCID

Affiliation:

1. ESPCI Paris 10 rue Vauquelin 75005 Paris France

2. Proteus by Seqens 70, Allée Graham Bell, Parc Georges Besse 30035 Nîmes Cedex 1 France

3. Seqens SAS, 21 Chemin de la Sauvegarde 21 Ecully Parc Ecully 69130 France

Abstract

AbstractEnantioselective reduction of cyclobutenones to optically active cyclobutanones has been achieved by using whole‐cell overexpressing Seqenzym ene‐reductases (EREDs). By using these enzymes, trans‐cyclobutanones were isolated in good yields and with enantiomeric excesses up to 99%.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202400417

Reference55 articles.

1. [2 + 2]-Cycloaddition-derived cyclobutane natural products: structural diversity, sources, bioactivities, and biomimetic syntheses

2. Cyclobutanes in Small‐Molecule Drug Candidates

4. Dancing on Ropes ‐ Enantioselective Functionalization of Preformed Four‐Membered Carbocycles

5. Advances in the catalytic asymmetric synthesis of quaternary carbon containing cyclobutanes

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