Harnessing Visible Light for the Synthesis of <i>N</i>‐Aryl Oxazolidines: Organocatalyzed Tandem Decarboxylation‐Cyclization-Reference-Cited by-同舟云学术

Harnessing Visible Light for the Synthesis of N‐Aryl Oxazolidines: Organocatalyzed Tandem Decarboxylation‐Cyclization

Published:2023-11-16 Issue:24 Volume:365 Page:4502-4506
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Udari Ganesh¹²,Murugesh V.¹,Sabarinathan Nagaraj¹,Sridhar B.²³,Prakash Singh Surya¹²^ORCID

Affiliation:

1. Department of Polymers and Functional Materials CSIR-Indian Institute of Chemical Technology (CSIR-IICT) Hyderabad 500 007 India

2. Academy of Scientific and Innovative Research (AcSIR) Ghaziabad 201 002 India

3. Department of Analytical & Structural Chemistry CSIR-Indian Institute of Chemical Technology Hyderabad 500007 India

Abstract

AbstractHerein, we have developed an organophotocatalyzed, visible‐light mediated tandem decarboxylation‐cyclization method. The Eosin‐Y as organophotocatalyst drives photoredox tandem protocol to construct C−N, C−O, and C−C bonds in a single operation. The reaction mechanism proceeds through decarboxylation followed by amino alcohol intermediate formation from N‐arylglycine and formaldehyde followed by cyclization with another formaldehyde delivers N‐arylloxazolidine derivatives.

Publisher

Wiley

Subject

General Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202300889

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