Affiliation:
1. Laboratoire de Chimie Moléculaire École Polytechnique Institut Polytechnique de Paris, CNRS Route de Saclay 91128 Palaiseau cedex France
Abstract
AbstractCross‐electrophilic coupling of various benzyl sulfonium salts with Callyl−O electrophiles is described using a simple Co−Mn catalytic system. This catalytic system is able to activate both the stable Csp3−S bond of sulfonium salts and the Csp3−O bond of allylic acetate or ether under mild reaction conditions to form various functionalized alkyl olefinic compounds. Allyl methyl ethers were employed for the first time in transition metal‐catalyzed cross‐electrophilic coupling to build Csp3−Csp3 bonds. Preliminary mechanistic studies suggested the involvement of benzyl radicals generated from C−S bond cleavage through a single electron transfer.
Funder
Linz Center of Mechatronics
China Scholarship Council
Institut Polytechnique de Paris
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献