Affiliation:
1. Key Laboratory for Green Organic Synthesis and Application of Hunan Province Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education College of Chemistry Xiangtan University Xiangtan 411105
2. School of Chemistry and Chemical Engineering Henan Normal University Xinxiang 453007 People's Republic of China
Abstract
AbstractHerein, we developed a rhodium(III)‐catalyzed synthesis of indenones from 2‐aryl‐3‐nitrosoindoles and alkynes in a redox‐neutral manner. The reaction did not require harsh conditions or any external oxidants. Mechanistic experiments and DFT calculation revealed that the reaction involved directed C−H activation, dearomative spirocyclization, N−O/C−C bond cleavage and ketimine hydrolysis cascade processes.
Funder
National Natural Science Foundation of China
Cited by
2 articles.
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