Affiliation:
1. School of Chemistry and Chemical Engineering Shandong University of Technology Zibo Shandong 255000 People's Republic of China
2. School of Life Sciences and Medical Shandong University of Technology Zibo Shandong 255000 People's Republic of China
3. Jiangsu Collaborative Innovation Center of Chinese Medicinal Resources Industrialization College of Pharmacy Nanjing University of Chinese Medicine Nanjing Jiangsu 210023, P People's Republic of China
Abstract
AbstractThe reaction of chlorosilanes with organometallic reagents is an old and well‐developed approach to organosilicon compounds, however, its application was limited due to the sensitivity of organometallic reagents to air, water. Here we display a mechanochemical access to arylsilanes via Barbier‐type reaction of chlorosilanes with aryl halide with magnesium. By treatment of the two halides with Mg powder under electromagnetic milling, a series of arylsilanes are obtained within 15 minutes. Taking the advantages of the electromagnetic milling, this protocol features transition‐metal free, good functional group tolerance, air stable and mild conditions.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Shandong Province
Cited by
1 articles.
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