Affiliation:
1. Chemistry of Interfaces Luleå University of Technology Luleå Sweden
2. School of Materials Science and Engineering/Herbert Gleiter Institute of Nanoscience Nanjing University of Science and Technology Nanjing China
Abstract
AbstractThe electrochemical and charge storage performance of a fluorine‐free structurally flexible hybrid pyrrolidinium‐based ionic liquid electrolyte (HILE) in a symmetric graphite‐based supercapacitor is thoroughly investigated. The HILE revealed thermal decomposition at above 230°C, a glass transition (Tg) temperature of below −70°C, and ionic conductivity of 0.16 mS cm−1 at 30°C. The chemical and electrochemical properties are investigated using a systematic variable temperature 1H and 31P NMR spectroscopy and diffusometry, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charge‐discharge (GCD). The supercapacitor demonstrated a notable specific capacitance of 186 F g−1 at a scan rate of 1 mV s−1 and a specific capacitance of 122 F g−1 at a current density of 0.5 A g−1. The maximum energy density of 48.8 Wh kg−1, a power density of 450 W kg−1 at a current density of 0.5 A g−1, and a potential window of 4 V were obtained. Altogether, this study demonstrates that the new HILE can be used in symmetric graphite‐based supercapacitors over a wide potential window of 4 V and a temperature range from −20°C to 90°C.
Subject
Renewable Energy, Sustainability and the Environment,Energy Engineering and Power Technology