Author:
Roden Brian A.,Gennaiou Kyriaki,Kourgiantaki Maria,Mazaraki Kalliopi,Zografos Alexandros L.
Abstract
Abstract
image
[
32133‐82‐7
]
C
30
H
20
F
12
O
2
S
(MW 672.57)
InChI =
1S/C30H20F12O2S/c31‐27(32,33)25(28(34,35)36,21‐13‐5‐1‐6‐14‐21)43‐45(23‐17‐9‐3‐10‐18‐23,24‐19‐11‐4‐12‐20‐24)44‐26(29(37,38)39,30(40,41)42)22‐15‐7‐2‐8‐16‐22/h1‐20H
InChIKey =
RMIBJVUYNZSLSD‐UHFFFAOYSA‐N
(dehydration of alcohols;
2
synthesis of epoxides and cyclic ethers;
3
cleavage of amides;
5
oxidation of amines
6
)
Physical Data
: mp 107–109 °C.
Solubility
: sol ether, benzene, acetone, alcohols.
Form Supplied in
: white crystals.
Analysis of Reagent Purity
: NMR, IR.
Preparative Method
: by the reaction of the potassium salt of 1,1,1,3,3,3‐hexafluoro‐2‐phenylisopropanol with diphenyl sulfide in the presence of chlorine in ether at −78 °C.
1
a
Handling, Storage, and Precautions
: avoid moisture; readily hydrolyzed; stable at rt; decomposes slowly at rt in solution.