Affiliation:
1. Department of Polymer Science and Engineering School of Chemistry and Materials Science University of Science and Technology of China Hefei Anhui 230026 China
2. Key Laboratory of Precision and Intelligent Chemistry University of Science and Technology of China Hefei Anhui 230026 China
Abstract
AbstractChiroptical materials with strong and switchable circularly polarized luminescence (CPL) properties have gained considerable interest due to their feasible applications in optoelectronic devices, sensing, and information encryption. However, in most cases, their luminescence dissymmetry factor (glum) and figure of merit (FOM) values remain very low. Herein, a novel heterogeneous twisted‐stacking structure is proposed, which endows with strong CPL amplification (a maximum of ≈15‐fold enhancement) over traditional homogeneous structures and a high FOM value up to 0.11. Interestingly, their CPL performance (including the sign, magnitude, and spectral position) and the FOM values can be precisely manipulated or even inversed by simply uniaxial stretching, since the phase retardation of the anisotropic poly (vinyl alcohol) layer can be controlled. Moreover, by combining with the viologen gel electrochromic system, the in situ voltage‐driven switching and patterning of the CPL signal can be successfully achieved, with low operation voltage and good cycling stability. This study provides a creative strategy for fabricating strong and electrical switchable CPL‐active materials, which promise new opportunities in miniaturized smart electrochiroptical devices for future information technology.
Funder
Chinese Academy of Sciences
National Natural Science Foundation of China
Subject
Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials