Gradient Dion‐Jacobson Phase Stable Quasi‐2D Perovskite@Graphene Hybrid for High Responsivity Photodetectors

Author:

Hegde Sapthami1,Sridhar Varun1,Chen Ruei San2,Chattopadhyay Surojit1ORCID

Affiliation:

1. Institute of Biophotonics National Yang Ming Chiao Tung University 155, sec‐2 Li Nong Street Taipei 112 Taiwan

2. Graduate Institute of Applied Science and Technology National Taiwan University of Science and Technology Section 4, Keelung Rd, Daan District Taipei 106 Taiwan

Abstract

AbstractQuasi‐(2D) formamidinium lead‐iodide (FAPbI3) perovskites are winsome materials for high‐performance photodetectors (PDs). Between Ruddlesden‐Popper (RP) and Dion‐Jacobson (DJ) phases, the latter exhibits lower non‐radiative recombination and higher mobility compared to the relatively easily synthesized former. For efficient charge separation and transport, graphene‐assisted two‐terminal coplanar PD leveraging the DJ phase perovskite is proposed. Diamino octane (DAO), incorporated into 3D FAPbI3 perovskite, resulted in DJ phase [DAO(FA)n‐1PbnI3n+1], n being predefined integers 1≤ n ≤ ∞, demonstrating a vertical gradient heterostructure of n phases. Superior crystallinity and thermal stability of the quasi‐2D films are confirmed via synchrotron‐based studies. Band‐edge of the 3D film blue‐shifted consistently from 810 nm, while passing through the quasi‐2D phases, to ≈500 nm for the 2D phase. The dynamic range of photoresponsivity (R) of PDs reflected the absorption trend, with the 2D perovskite being infrared blind. Graphene's high carrier mobility coupled with the perovskite's high absorbance resulted in an unprecedented high R of ≈107 A W−1 and specific detectivity of 9.77 × 1016 Jones under 42.25 nW cm−2 of 405 nm illumination for the predefined = 2 film. This underscores the potential of the DJ phase quasi‐2D perovskite@graphene in realizing stable, sensitive, and spectrally tunable PDs.

Funder

National Synchrotron Radiation Research Center

Ministry of Science and Technology, Taiwan

Publisher

Wiley

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