Affiliation:
1. Department of Electrical and Computer Engineering University of Nebraska‐Lincoln Lincoln NE 68588 USA
2. Onto Innovation Inc. Wilmington MA 01887 USA
3. J.A. Woollam Co., Inc. Lincoln NE 68508 USA
4. Fraunhofer Institute for Microstructure of Materials and Systems (IMWS) 106120 Halle (Saale) Germany
5. Department of Electrical Engineering The Pennsylvania State University University Park State College PA 16803 USA
6. Solid State Physics and NanoLund Lund University P.O. Box 118 Lund 22100 Sweden
Abstract
AbstractNanostructures represent a frontier where meticulous attention to the control and assessment of structural dimensions becomes a linchpin for their seamless integration into diverse technological applications. However, determining the critical dimensions and optical properties of nanostructures with precision still remains a challenging task. In this study, by using an integrative and comprehensive methodical series of studies, the evolution of the depolarization factors in the anisotropic Bruggeman effective medium approximation (AB‐EMA) is investigated. It is found that these anisotropic factors are extremely sensitive to the changes in critical dimensions of the nanostructure platforms. In order to perform a systematic characterization of these parameters, spatially coherent, highly‐ordered slanted nanocolumns are fabricated from zirconia, silicon, titanium, and permalloy on silicon substrates with varying column lengths using glancing angle deposition (GLAD). In tandem, broad‐spectral range Mueller matrix spectroscopic ellipsometry data, spanning from the near‐infrared to the vacuum UV (0.72–6.5 eV), is analyzed with a best‐match model approach based on the anisotropic Bruggeman effective medium theory. The anisotropic optical properties, including complex dielectric function, birefringence, and dichroism, are thereby extracted. Most notably, the research unveils a generalized, material‐independent inverse relationship between depolarization factors and column length. It is envisioned that the presented scaling rules will permit accurate prediction of optical properties of nanocolumnar thin films improving their integration and optimization for optoelectronic and photonic device applications. As an outlook, the highly porous nature and extreme birefringence properties of the fabricated columnar metamaterial platforms are further explored in the detection of nanoparticles from the cross‐polarized integrated spectral color variations.
Funder
National Science Foundation
Air Force Office of Scientific Research
Materials Research Science and Engineering Center, University of Nebraska
American Chemical Society Petroleum Research Fund
Deutsche Forschungsgemeinschaft
J. A. Woollam Foundation
Office of Experimental Program to Stimulate Competitive Research