A Pick‐and‐Place Technology Enabled, Mechanically Programmable, Spiral Optical Waveguides Integrated Hybrid Circuits from Four Extremely Pseudo‐Plastic Organic Crystals for Visible Spectral Band Tunability

Abstract

AbstractIn the field of silicon photonics, highly compact and miniature high‐density circuits are achieved by precisely shaping millimeter‐long waveguides into spiral configurations. Organic photonics, on the other hand, takes advantage of mechanically flexible crystal spiral waveguides (SWs) within organic photonic circuits. These SWs offer versatility, enabling precise control over light paths and mechanical programmability. This study introduces an innovative pick‐and‐place technique for constructing various organic spiral waveguides (OSWs) with different geometries, such as Cornu, Archimedean, elliptical, rectangular, four‐sided polygons, and three‐sided polygons. Additionally, this method allows for the creation of optically reprogrammable photonic circuits. Custom‐synthesized flexible crystals are used, including blue‐emitting (Z)−3‐(4‐(9H‐carbazol‐9‐yl)phenyl)−2‐(3,5‐bis(trifluoromethyl)phenyl)acrylonitrile (Cz‐2CF3), green‐emitting (E)−1‐(((5‐bromopyridin‐2‐yl)imino)methyl)naphthalene‐2‐ol (BPyIN), cyan‐emitting 9,10‐dibromo anthracene (DBA), and red‐emitting 4,7‐bis(4‐octylthiophen‐2‐yl)benzo[c][1,2,5]thiadiazole (BTD). Systematically integrating a Cz‐2CF3 OSW (with two ports for optical signal routing in clockwise/counterclockwise directions) with DBA and BTD waveguides produces multi‐color hybrid photonic circuits with customizable optical functions, tailored to specific design needs. The number of output ports can be dynamically adjusted through mechanical programming by coupling crystals tip‐to‐tip when replacing the DBA waveguide with a BPyIN waveguide using the pick‐and‐place technology. This mechanically programmable hybrid spiral photonic circuit seamlessly operates across the entire visible spectral bandwidth, making it valuable for various applications, including high‐fidelity sensing, spectrometer components, and intelligent circuitry.