Core‐Shell Micro‐ and Nano‐Structures for The Modification of Light‐Surface Interactions

Author:

Yeo Reuben J.1ORCID,Yeo Jayven C. C.1ORCID,Yu Tan Sze1,Sng Anqi1,Tomczak Nikodem1ORCID,Muiruri Joseph Kinyanjui2,Wang Suxi1ORCID,Wang Pei1,Thitsartarn Warintorn1ORCID,Wang Fuke1ORCID,Ye Enyi123ORCID,Li Zibiao124ORCID,Xu Jianwei125ORCID,Loh Xian Jun125ORCID,Zhu Qiang126ORCID

Affiliation:

1. Agency for Science, Technology and Research (A*STAR) Institute of Materials Research and Engineering (IMRE) 2 Fusionopolis Way, Innovis #08‐03 Singapore 138634 Singapore

2. Agency for Science, Technology and Research (A*STAR) Institute of Sustainability for Chemicals, Energy and Environment (ISCE2) 1 Pesek Road, Jurong Island Singapore 627833 Singapore

3. Division of Physics and Applied Physics, School of Physical and Mathematical Sciences Nanyang Technological University 50 Nanyang Avenue Singapore 639798 Singapore

4. Department of Physics National University of Singapore 2 Science Drive 3 Singapore 117551 Singapore

5. Department of Chemistry National University of Singapore 3 Science Drive 3 Singapore 117543 Singapore

6. School of Chemistry, Chemical Engineering and Biotechnology Nanyang Technological University 21 Nanyang Link Singapore 637371 Singapore

Abstract

AbstractControlling how a material interacts with light is key to optimizing its optical properties to fit a desired function or application. The most straightforward approach is to chemically or physically modify the surface exposed to incident light. An effective method of surface modification is based on the addition of core‐shell structures at the surface. Of particular importance to many technological applications are core‐shell structures with dimensions comparable to the wavelengths of light extending from the UV up to the near‐IR region of the electromagnetic spectrum, which coincides with the major part of the solar spectrum. Surface modification approaches to tailor the optical properties of materials in this range of wavelengths are increasingly relevant in the context of materials and devices used in sustainable energy applications, such as solar cells and heat‐reflective paints. These materials are useful to mitigate the current energy and climate crises by allowing for enhanced energy harvesting and improved thermal management, respectively. Here, recent progress in the fabrication and application of core‐shell micro‐/nano‐structures for the modification of light interaction with surfaces is highlighted. Some limitations and future directions for the design of core‐shell materials are also discussed.

Funder

Agency for Science, Technology and Research

Publisher

Wiley

Subject

Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials

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