Affiliation:
1. College of Materials and Chemistry & Chemical Engineering Chengdu University of Technology Chengdu 610059 China
2. School of Mechanical Engineering Institute for Advanced Materials Deformation and Damage from Multi‐Scale Chengdu University Chengdu 610106 China
3. Shenzhen Key Laboratory of Laser Engineering College of Physics and Optoelectronic Engineering Shenzhen University Shenzhen 518060 China
4. Faculty of Materials Science and Engineering Key Laboratory of Advanced Materials of Yunnan Province Kunming University of Science and Technology Kunming 650093 China
Abstract
AbstractThe development of highly stable and ultra‐long organic room temperature phosphorescence (RTP) materials holds great promise for applications in anti‐counterfeiting and information protection. To improve the encryption level, the exploration of organic materials with tunable phosphorescence and afterglow features is in urgent need. Hereby, a series of long‐lived organic systems with RTP is developed by incorporating benzocarbazole derivatives into a polyvinyl alcohol (PVA) matrix (BCz@PVA). Notably, the BCz@PVA film exhibits outstanding RTP behavior with an ultralong phosphorescence lifetime (τp) of 2.09 s, high phosphorescence quantum yield (Φp) of 46.335%, and an ultra‐long afterglow duration of 15 s. Moreover, the BCz@PVA film maintains excellent RTP performance even after being placed in ambient conditions for 60 days. Theoretical calculations reveal that the excellent RTP performance of BCz@PVA film is attributed to the stronger intermolecular interactions, the smaller energy gap (ΔEst) between the singlet and triplet states, and stable molecular stacking mode. Furthermore, color‐tunable photoluminescence (PL), distinct τp, and afterglow duration are successfully achieved by adjusting the position of the Br substituent on the benzene ring. Based on their diverse RTP performances and excellent stability, the corresponding BCz@PVA film provides successful application for multi‐level high‐security anti‐counterfeiting and information protection.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Sichuan Province
Natural Science Foundation of Yunnan Province
Subject
Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials
Cited by
1 articles.
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