Affiliation:
1. Department of Energy and Chemical Engineering Incheon National University 119 Academy‐ro, Yeonsu‐gu Incheon 22012 Republic of Korea
2. Graduate School of Integrated Energy‐AI School of Chemical Engineering Clean Energy Research Center Jeonbuk National University 567 Baekje‐daero Jeonju 54896 Republic of Korea
Abstract
AbstractConjugated polymers exhibit significant potential for use in gas sensors owing to their flexibility and straightforward preparation. However, the performance of organic gas sensors based on such materials is currently suboptimal owing to their poor charge‐transport properties and limited selectivity. To address this limitation, a novel strategy that involves blending a chemically modified metal–organic framework (MOF) material, UiO‐66, with a conjugated polymer is developed. The MOF porous material is chemically modified with polar nitrogen‐containing functional groups (amino and nitro groups) to create gas molecule adsorption sites. To evaluate the impact of these modifications on the sensing performance, experiments that combined the sensing performance with a density functional theory simulation are conducted. The findings reveal that gas sensors fabricated using an amine‐functionalized MOF blended with conjugated polymers exhibit significantly higher sensitivity than home polymer devices, the sensing performance of the UiO‐66‐NH2/P3HT blend film improved by a factor of two with a sensitivity of ≈2%/ppm and an LOD of 0.001 ppt. Additionally, these devices exhibit exclusive NO2‐sensing performance for other gases such as CO2 and SO2.
Funder
Incheon National University
Cited by
1 articles.
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