A Brilliant Magnetic Refrigerant Operating Near Liquid Helium Temperature: Enhanced Magnetocaloric Effect in Ferromagnetic EuTi0.75Al0.125Zr0.125O3

Author:

Xie Huicai1ORCID,Jiang Jiaxin12,Tian Lu13,Mo Zhaojun12ORCID,Liu Guodong3,Gao Xinqiang12,Shen Jun4,Liu Yao5

Affiliation:

1. Key Laboratory of Rare Earths Ganjiang Innovation Academy Chinese Academy of Sciences Ganzhou 341119 China

2. School of Rare Earths University of Science and Technology of China Hefei 230026 China

3. School of Materials Science and Engineering Hebei University of Technology Tianjin 300130 China

4. School of Mechanical Engineering Beijing Institute of Technology Beijing 100081 China

5. Key Laboratory for Liquid‐Solid Structural Evolution and Processing of Materials (Ministry of Education) Shandong University Jinan 250061 China

Abstract

AbstractRare earth‐based perovskites have become an attractive research interest in the field of cryogenic magnetic refrigerants due to their unique advantages in practical applications. The remarkable magnetocaloric effect (MCE) renders EuTiO3 a potential magnetic refrigerant in the liquid helium temperature range. More impressively, the tunability between antiferromagnetism (AFM) and ferromagnetism (FM) provides the feasibility of tailoring the magnetism and enhancing the magnetocaloric performance. In this study, the magnetism of EuTi0.75Al0.125Zr0.125O3 is investigated in depth through first‐principles calculations and experimental methods. Both theoretical calculations and experimental results reveal that it exhibits significant ferromagnetism due to the AFM‐FM magnetic transition promoted by the co‐substitution of Al and Zr. Lattice expansion and altered electronic interactions are responsible for the FM behavior, which leads to a significant enhancement of the MCE. With the field change of 0−1 T, the peak values of magnetic entropy change (−ΔSM), refrigerating capacity (RC), and adiabatic temperature change (ΔTad) reach 18.9 J kg−1 K−1, 77.7 J kg−1, and 7.4 K, respectively. More surprisingly, the values of maximum magnetic entropy change () and maximum adiabatic temperature change for EuTi0.75Al0.125Zr0.125O3 reach 11.4 J kg−1 K−1 and 3.7 K under the field change of 0−0.5 T, respectively. The remarkable magnetocaloric performance proves it to be a brilliant magnetic refrigerant operating near liquid helium temperature.

Funder

National Key Research and Development Program of China

National Science Fund for Distinguished Young Scholars

National Natural Science Foundation of China

Publisher

Wiley

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