Charged Domain Walls in BaTiO3 Crystals Emerging from Superdomain Boundaries

Abstract

AbstractPrevious experiments with barium titanate crystals have shown that electric field applied in the vicinity of its ferroelectric phase transition can be used to introduce peculiar ferroelectric domain walls, persisting to the ambient conditions: head‐to‐head charged walls compensated by the 2D electron gas. The present in situ optical observations allow the documentation of the early stage of this poling process in which the cubic and ferroelectric phases coexist, the latter being broken into multiple martensitic superdomains, separated by superdomain boundaries. It is revealed that the transient superdomains are subsequently converted into the regular ferroelectric domains, while the superdomain boundaries transform into the desired charged domain walls. In order to assign the observed transient domain patterns, to understand the shapes of the observed ferrolectric precipitates and their agglomerates as well as to provide the overall interpretation of the recorded domain formation process, the implications of the mechanical compatibility of the coexisting superdomain states are derived in the framework of the Wechsler–Lieberman–Read theory. These results also suggest that both the electric conductivity and interlinked motion of the superdomain boundaries and phase fronts are involved in the transport of the compensating charge carriers toward the charged domain wall location.