The unexpected formation of trans-β-lactams in the reaction of α-iminoesters (RNC(H)C(O)OR′) with diethylzinc. Crystal structure of trans -1-(N -t -butyl)-3-(N-t -butyl-N-ethylamino)-4- methoxycarbonylazetidin-2-one-Reference-Cited by-同舟云学术

The unexpected formation of trans-β-lactams in the reaction of α-iminoesters (RNC(H)C(O)OR′) with diethylzinc. Crystal structure of trans -1-(N -t -butyl)-3-(N-t -butyl-N-ethylamino)-4- methoxycarbonylazetidin-2-one

Published:1987 Issue:4 Volume:106 Page:132-134
ISSN:0165-0513
Container-title:Recueil des Travaux Chimiques des Pays-Bas
language:en
Short-container-title:Recl. Trav. Chim. Pays-Bas

Author:

van Vliet M. Robert P.,Klaver Wim J.,Jastrzebski Johann T. B. H.,van Koten Gerard,Goubitz Kees

Funder

Gist-Brocades N.V., The Netherlands

Publisher

Wiley

Subject

General Chemistry

Link

http://onlinelibrary.wiley.com/wol1/doi/10.1002/recl.19871060405/fullpdf

Reference28 articles.

1. An unexpected ethyl transfer reaction between Et2Zn and DI(t-Butyl)-glyoxaldiimine (t-BuDAB). Studies of the persistent [EtZn(t-BuDAB)] radical which is in equilibrium with its CC coupled dimer

2. Regioselective ethyl transfer reactions between Diethylzinc and 1,4-Dialkyl-1,4-diaza-1,3-butadienes: Synthesis of EtZn[R(et)NCHCHNR]

3. Stable 1,4-diaza-1,3-butadiene(α-diimine)-zinc and -aluminium radicals formed in single electron transfer reactions: their consequences for organic syntheses

4. Diazabutadienes as ligands

5. Novel reactions of substituted 1-aza-4-oxobutadienes (α-iminoketones) with diorganozinc reagents. Selective ethyl transfer in the Et2Zn/t-BuNC(H)C(Me)O system and x-ray crystal structure of [EtZ]2

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