Stereoisomerically Pure Trisubstituted Vinylaluminum Reagents and their Utility in Copper‐Catalyzed Enantioselective Synthesis of 1,4‐Dienes Containing Z or E Alkenes
Author:
Affiliation:
1. Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467 (USA), Fax: (+1) 617‐552‐1442
Publisher
Wiley
Subject
General Chemistry,Catalysis
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.200905223
Reference59 articles.
1. For examples of catalytic enantioselective vinyl additions to carbonyls see:
2. Synthesis of (R)-(-)-muscone by an asymmetrically catalyzed macrocyclization of an .omega.-alkynal
3. Catalytic Asymmetric Reductive Coupling of Alkynes and Aldehydes: Enantioselective Synthesis of Allylic Alcohols and α-Hydroxy Ketones
4. Catalytic Asymmetric Vinylation of Ketones
5. Enantioselective Alkenylation and Phenylation Catalyzed by a Chiral CuF Complex
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