Surface saturation current densities of perovskite thin films from Suns‐photoluminescence quantum yield measurements

Author:

Chin Robert Lee1ORCID,Soufiani Arman Mahboubi1,Fassl Paul2,Zheng Jianghui13,Choi Eunyoung1,Ho‐Baillie Anita13ORCID,Paetzold Ulrich W.2,Trupke Thorsten1ORCID,Hameiri Ziv1ORCID

Affiliation:

1. The University of New South Wales Sydney Australia

2. Karlsruhe Institute of Technology (KIT) Karlsruhe Germany

3. The University of Sydney Sydney Australia

Abstract

AbstractWe present a simple yet powerful analysis of Suns‐photoluminescence quantum yield measurements that can be used to determine the surface saturation current densities of thin film semiconductors. We apply the method to state‐of‐the‐art polycrystalline perovskite thin films of varying absorber thickness. We show that the non‐radiative bimolecular recombination in these samples originates from the surfaces. To the best of our knowledge, this is the first study to demonstrate and quantify non‐linear (bimolecular) surface recombination in perovskite thin films.

Funder

Australian Renewable Energy Agency

Publisher

Wiley

Subject

Electrical and Electronic Engineering,Condensed Matter Physics,Renewable Energy, Sustainability and the Environment,Electronic, Optical and Magnetic Materials

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