Visible Light‐Driven N–F‐Codoped TiO2 for Photocatalysts as Potential Application to Wastewater Treatment

Author:

Pham Toan Minh12,Bui Khang Quang12,Le Dien Vinh3,Pham Hau Quoc45,Huynh Tai Thien6,Ngo Thang Manh12,Ho Van Thi Thanh6

Affiliation:

1. Ho Chi Minh City University of Technology (HCMUT) 268 Ly Thuong Kiet, District 10 72506 Ho Chi Minh City Viet Nam

2. Vietnam National University 700000 Ho Chi Minh City Viet Nam

3. Lawrence S. Ting High School 80 Nguyen Duc Canh, Tan Phong, District 7 700000 Ho Chi Minh City Viet Nam

4. Duy Tan University Future Materials & Devices Lab., Institute of Fundamental and Applied Sciences 700000 Ho Chi Minh City Viet Nam

5. Duy Tan University Faculty of Environmental and Chemical Engineering 550000 Da Nang Viet Nam

6. Hochiminh City University of Natural Resources and Environment (HCMUNRE) 236B Le Van Sy, Tan Binh District 72107 Ho Chi Minh City Viet Nam

Abstract

AbstractN–F‐codoped TiO2 materials were successfully fabricated by a hydrothermal method without any capping agent and further heat treatment. The results indicate interstitial N3− ion doping and the surface‐adsorbed F ion on the TiO2 surface. By introducing N and F into the TiO2 lattice, the band gap of the obtained material is significantly reduced compared to the undoped TiO2. Moreover, the light absorption ability of the material was demonstrated to extend to visible light regions, contributing to the better photocatalytic activity. Furthermore, the sample with the NH4F/TiCl4 precursor molar ratio of 2:1 displayed the greatest photocatalytic activity with visible radiation. This study provides a new pathway to synthesize a novel photocatalyst having great potential for future applications.

Funder

Viet Nam National University Ho Chi Minh City

Publisher

Wiley

Subject

Industrial and Manufacturing Engineering,General Chemical Engineering,General Chemistry

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