Low Contact Resistivity of Bi2Te3‐Based Films and Metals Interfaces Enabled by Orientation Regulation

Author:

Dong Guoying12,Xiong Yang2,Zhao Linghao2,Feng Jianghe2,Li Juan2,Gao Shufang1,Liu Ruiheng2ORCID

Affiliation:

1. School of Physics and Optoelectronic Engineering Yangtze University 1 Xueyuan Road Jingzhou 434023 China

2. Shenzhen Institute of Advanced Electronic Materials Shenzhen Institute of Advanced Technology Chinese Academy of Sciences No.4‐2‐13, Longhengsi Road, Shenzhen Baoan 518055 China

Abstract

AbstractThe contact resistivity originating from the metal–semiconductor interface is a crucial factor for conversion efficiency of thermoelectric films devices. Due to anisotropic nature of state‐of‐art Bi2Te3 films, the contact resistivity also needs to match with the different orientations in/out‐plane film configurations. Here, a series of bismuth telluride (Bi2Te3) films with different orientations are deposited, and the contact resistivity between Ti/Cr/Cu and Bi2Te3‐based films is studied in detail. The increased (00l) orientation can effectively reduce the contact resistivity mainly due to the enhanced Tunneling effect. Finally, a low contact resistivity of 0.84 µΩ cm2 is observed in highly (00l)‐orientated Bi2Te3 film in contact with Cr. This work provides an effective method to control contact resistivity by adjusting the orientation of film, and also provides guidance on how to further improve the performance of thin film‐TEDs with different configurations.

Funder

Postdoctoral Research Foundation of China

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Natural Science Foundation of Shenzhen Municipality

Publisher

Wiley

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