Design and research of high‐performance electromagnetic interference shielding GO/NiNCs/PMMA microcellular foams

Abstract

AbstractHigh performance electromagnetic (EM) interference shielding composites are of high demand due to increasing EM wave radiation pollution. In this work, GO/NiNCs/PMMA microcellular foams with different GO/NiNCs gradient and 3D conductive filler framework were fabricated by thermal reduction and supercritical CO2 foaming process. With the crosslink of 1D NiNCs and 2D GO sheets, GO/NiNCs framework with electrical conductivity varied from 1.15 × 10−4 to highest 1.09 × 10−1 S/m is fabricated, exhibiting absorption‐dominated electromagnetic interference shieling effectiveness (EMI SE) of 53.62 dB and specific EMI SE of 48.44 dB g−1 cm3 in X‐band. The density of GO/NiNCs/PMMA microcellular foams achieved lowest value of 0.623 g/cm3. Moreover, the foams showed excellent thermal conductivity and compressive strength of 178.76 MPa, indicating excellent application potential in aerospace and electronic field. The thermoplastic polymer matrix also indicates great potential in recycle of the foam material.