A DFT-Based Theoretical Investigation of the Mechanism of the PtCl2-Mediated Cycloisomerization of Allenynes

Author:

Soriano Elena,Marco-Contelles Jos�

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

Reference50 articles.

1. Mechanistic aspects of transition metal catalysed 1,6-diene and 1,6-enyne cycloisomerisation reactions

2. On the Mechanism of Carbohydroxypalladation of Enynes. Additional Insights on the Cyclization of Enynes with Electrophilic Metal Complexes

3. The Effect of a Hydroxy Protecting Group on the PtCl2-Catalyzed Cyclization of Dienynes—A Novel, Efficient, and Selective Synthesis of Carbocycles Acknowledgement is made to the EU for the COST D12 Action “Cascade Free Radical Reactions” and for a short-term scientific mission to Madrid (EM). We thank Nieves Arroyo (CSIC) for preliminary experiments, Dr. J. Vaissermann (UPMC) for the X-ray analysis of 3 e, Dr. M. L. Jimeno (CNQO) for NMR studies on 3 a, Dr. M.-N. Rager (ENSCP) for NMR studies on 3 h, 6, and 11, and Matthieu Bernard (UPMC) for performing some of the experiments. We also thank Dr. Emmanuel Lacôte and Dr. Henri Rudler (UPMC) for helpful discussions.

4. The Effect of a Hydroxy Protecting Group on the PtCl2-Catalyzed Cyclization of Dienynes—A Novel, Efficient, and Selective Synthesis of Carbocycles Acknowledgement is made to the EU for the COST D12 Action “Cascade Free Radical Reactions” and for a short-term scientific mission to Madrid (EM). We thank Nieves Arroyo (CSIC) for preliminary experiments, Dr. J. Vaissermann (UPMC) for the X-ray analysis of 3 e, Dr. M. L. Jimeno (CNQO) for NMR studies on 3 a, Dr. M.-N. Rager (ENSCP) for NMR studies on 3 h, 6, and 11, and Matthieu Bernard (UPMC) for performing some of the experiments. We also thank Dr. Emmanuel Lacôte and Dr. Henri Rudler (UPMC) for helpful discussions.

5. Mechanistic Dichotomy in CpRu(CH3CN)3PF6 Catalyzed Enyne Cycloisomerizations

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