The Impact of Weak CH⋅⋅⋅Rh Interactions on the Structure and Reactivity oftrans-[Rh(CO)2(phosphine)2]+: An Experimental and Theoretical Examination-Reference-Cited by-同舟云学术

The Impact of Weak CH⋅⋅⋅Rh Interactions on the Structure and Reactivity oftrans-[Rh(CO)2(phosphine)2]+: An Experimental and Theoretical Examination

Published:2008-09-19 Issue:27 Volume:14 Page:8183-8194
ISSN:0947-6539
Container-title:Chemistry - A European Journal
language:en
Short-container-title:Chem. Eur. J.

Author:

Montag Michael,Efremenko Irena,Cohen Revital,Leitus Gregory,Shimon Linda J. W.,Diskin-Posner Yael,Ben-David Yehoshoa,Martin Jan M. L.,Milstein David

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

Reference77 articles.

1. Understanding and exploiting C–H bond activation

2. C-H Bond Functionalization in Complex Organic Synthesis

3. The Unexpected Role of CO in CH Oxidative Addition by a Cationic Rhodium(I) Complex

4. Angew. Chem. Int. Ed. 2007, 46, 1901-1904.

5. CO is usually regarded as a strong π-accepting ligand and is therefore expected to inhibit processes that increase the formal oxidation state of the metal center, such as oxidative addition.

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