A voltammetrically potentionmetric pH sensor based on multiply hydroxylated porphyrin

Author:

Lin Fan1ORCID,Xu Ying1,Li Xueni1,Wang Yilin1,Ru Yulu1,Wang Dandan1,Zhou Xiaoshun1,Shao Yong1

Affiliation:

1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, College of Chemistry and Materials Science Zhejiang Normal University Jinhua 321004 P. R. China

Abstract

AbstractUsing voltammetry to readout potentiometrically the solution acidity requires easy pH tunability of the probe's redox properties. In this work, tri‐hydroxyphenyl porphyrin (POH3) was synthesized as the electrochemically active probe to develop a voltammetrically potentiometric sensor (VPS) with a pH‐sensitive response. By comparing POH3 with control di‐ and mono‐hydroxyphenyl porphyrins (POH2 and POH1), we found that protonation of the pyrrole macrocycle, electron communication of the para‐hydroxyl groups with the pyrrole nitrogens during structure tautomerization, and the presence of multiple ionizable hydroxyl groups are the critical factors to report reversibly the pH‐sensitive VPS response at the appropriate potential range. Common metal ions have negligible effects on the sensor performance. In comparison to the conventional potentiometric sensor (CPS), our VPS strategy benefits from the advantage that the electrode modification is not required. Thus, the complex phase boundary models necessary for CPS are unnecessarily involved in explaining the potential response.

Funder

National Natural Science Foundation of China

Publisher

Wiley

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