Structural control of nickel nanowire arrays for use as non‐enzymatic glucose sensors

Abstract

AbstractA series of non‐enzymatic electrochemical glucose sensors were prepared by template‐assisted electrodeposition of nickel to produce nickel nanowire arrays (NiNWAs) of varying lengths. These electrodes were analyzed for their performance as non‐enzymatic glucose sensors, in order to explore the relationship between nanowire structure and electrochemical sensor performance. All of the NiNWAs, regardless of length, had linear responses to glucose in the 0.05–10 mM range. However, an inverse relationship between wire length and sensitivity was observed: the shortest of the NiNWAs had a sensitivity of 160 μA mM−1 cm−2, while the longest NiNWA had a sensitivity of only 100 μA mM−1 cm−2. This indicates that, with no other change to material parameters, choosing an optimum length of nanowire provides significant improvement in performance. No change in electrochemical mechanism was observed by cyclic voltammetry, and no significant loss of selectivity was observed with varying nanowire length. This study demonstrates that the structural optimization of an electrode can provide significant performance enhancement for nickel‐based electrochemical sensors.