A ultra‐low viscosity stearic acid emulsion prepared by lauric acid as waterproof agent for cement mortar

Author:

Huang Haowei12ORCID,Wu Liangliang2,Wang Gang2,Wang Xianjun2,Xie Yunchuan1

Affiliation:

1. School of Chemistry, Xi'an Key Laboratory of Sustainable Energy Material Chemistry Xi'an Jiaotong University Xi'an China

2. Department of Research and Development Keshun Waterproof Technology Co., Ltd Foshan China

Abstract

AbstractSafe building structures cannot be achieved without reliable waterproofing engineering. To address the susceptibility of concrete materials to water leakage, a low‐viscosity stearic acid emulsion has been developed as a waterproofing agent for mortar. By introducing lauric acid, the formation of stearic acid crystals in water could be effectively prevented, resulting in a stearic acid emulsion with a viscosity of only 24 mPa·s. It is found that the best overall performance was achieved when the ratio (R) of lauric acid to stearic acid was 2/3. This emulsion has the least effect on mortar fluidity and setting time. The as‐prepared modified mortar possessed the highest compressive strength (127% of the blank) and the lowest water absorption at 48 h (37% of the blank). X‐ray diffraction (XRD), Fourier‐transform infrared spectroscopy (FTIR), energy‐dispersive x‐ray spectroscopy (EDS), scanning electron microscopy (SEM), dynamic light scattering (DLS) particle size analysis, and water contact angle measurements were used to investigate the mechanism of stearic acid emulsion's modification. It is determined that the stearic acid emulsions successfully modified the internal and external hydrophobicity of the mortar by chemical action with calcium hydroxide.

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,Surfaces, Coatings and Films,General Chemistry

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1. Synthesis and Properties of Vinyl Ether and Acrylonitrile Copolymers;Macromolecular Chemistry and Physics;2024-03-23

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