Total Synthesis of the Spliceosome Modulator Pladienolide B via Asymmetric Alcohol‐Mediated syn ‐ and anti ‐Diastereoselective Carbonyl Crotylation
Author:
Affiliation:
1. University of Texas at Austin Department of Chemistry 105 E 24th St. (A5300) Austin TX 78712-1167 USA
Funder
Welch Foundation
National Institute of General Medical Sciences
Publisher
Wiley
Subject
General Medicine
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.202103845
Reference69 articles.
1. For isolation and structure determination of pladienolides A–G see:
2. Pladienolides, New Substances from Culture of Streptomyces platensis Mer-11107 I. Taxonomy, Fermentation, Isolation and Screening
3. Pladienolides, New Substances from Culture of Streptomyces platensis Mer-11107 II. Physico-chemical Properties and Structure Elucidation
4. Stereochemistry of Pladienolide B
5. For isolation and structure determination (via total synthesis) of FD-895 see:
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1. Stereo‐ and Site‐Selective Crotylation of Alcohol Proelectrophiles via Ruthenium‐Catalyzed Hydrogen Auto‐Transfer Mediated by Methylallene and Butadiene;Angewandte Chemie International Edition;2022-11-02
2. Stereo‐ and Site‐Selective Crotylation of Alcohol Proelectrophiles via Ruthenium‐Catalyzed Hydrogen Auto‐Transfer Mediated by Methylallene and Butadiene;Angewandte Chemie;2022-11-02
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