Affiliation:
1. Department of Chemistry Indian Institute of Science Education and Research Bhopal Bhopal Bypass Road, Bhauri Bhopal— 462 066 India
Abstract
AbstractHerein, we disclose the first report of 1,2‐difunctionalization of C−C multiple bonds using electrochemical gold redox catalysis. By adopting the electrochemical strategy, the inherent π‐activation and cross‐coupling reactivity of gold catalysis are harnessed to develop the oxy‐alkynylation of allenoates under external‐oxidant‐free conditions. Detailed mechanistic investigations such as 31P NMR, control experiments, mass studies, and cyclic voltammetric (CV) analysis have been performed to support the proposed reaction mechanism.
Funder
Science and Engineering Research Board
Board of Research in Nuclear Sciences