Electrochemical Gold‐Catalyzed 1,2‐Difunctionalization of C−C Multiple Bonds**

Author:

Kumar Anil1ORCID,Shukla Khyati1ORCID,Ahsan Salman1ORCID,Paul Amit1ORCID,Patil Nitin T.1ORCID

Affiliation:

1. Department of Chemistry Indian Institute of Science Education and Research Bhopal Bhopal Bypass Road, Bhauri Bhopal— 462 066 India

Abstract

AbstractHerein, we disclose the first report of 1,2‐difunctionalization of C−C multiple bonds using electrochemical gold redox catalysis. By adopting the electrochemical strategy, the inherent π‐activation and cross‐coupling reactivity of gold catalysis are harnessed to develop the oxy‐alkynylation of allenoates under external‐oxidant‐free conditions. Detailed mechanistic investigations such as 31P NMR, control experiments, mass studies, and cyclic voltammetric (CV) analysis have been performed to support the proposed reaction mechanism.

Funder

Science and Engineering Research Board

Board of Research in Nuclear Sciences

Publisher

Wiley

Subject

General Medicine

Reference77 articles.

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