Affiliation:
1. College of Chemical Engineering Zhejiang University of Technology Hangzhou 310014 China
2. State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou 730000 China
Abstract
AbstractReported here is an efficient and simple ether‐directed iridium‐catalyzed enantioselective C(sp3)−H borylation of cyclopropanes. Various functional groups were well‐tolerated, affording a vast array of chiral cyclopropanes with high enantioselectivities. We also demonstrated that the turnover numbers of the current reaction could be up to 335.
Funder
National Key Research and Development Program of China
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province