Affiliation:
1. Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 China
Abstract
AbstractThe artificial solid electrolyte interphase (SEI) plays a pivotal role in Zn anode stabilization but its long‐term effectiveness at high rates is still challenged. Herein, to achieve superior long‐life and high‐rate Zn anode, an exquisite electrolyte additive, lithium bis(oxalate)borate (LiBOB), is proposed to in situ derive a highly Zn2+‐conductive SEI and to dynamically patrol its cycling‐initiated defects. Profiting from the as‐constructed real‐time, automatic SEI repairing mechanism, the Zn anode can be cycled with distinct reversibility over 1800 h at an ultrahigh current density of 50 mA cm−2, presenting a record‐high cumulative capacity up to 45 Ah cm−2. The superiority of the formulated electrolyte is further demonstrated in the Zn||MnO2 and Zn||NaV3O8 full batteries, even when tested under harsh conditions (limited Zn supply (N/P≈3), 2500 cycles). This work brings inspiration for developing fast‐charging Zn batteries toward grid‐scale storage of renewable energy sources.
Funder
National Natural Science Foundation of China
Basic and Applied Basic Research Foundation of Guangdong Province
Cited by
2 articles.
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