Enantioselective Total Synthesis of (−)‐Limaspermidine and (−)‐Kopsinine by a Nitroaryl Transfer Cascade Strategy
Author:
Affiliation:
1. Department of Chemistry and Pharmaceutical Sciences Amsterdam Institute of Molecular and Life Sciences (AIMMS) De Boelelaan 1108 1081 HZ Amsterdam The Netherlands
Funder
Nederlandse Organisatie voor Wetenschappelijk Onderzoek
Publisher
Wiley
Subject
General Medicine
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.202210592
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4. Racemic syntheses:
5. Use of aza-Cope rearrangement-Mannich cyclization reactions to achieve a general entry to Melodinus and Aspidosperma alkaloids. Stereocontrolled total syntheses of (.+-.)-deoxoapodine, (.+-.)-meloscine, and (.+-.)-epimeloscine and a formal synthesis of (.+-.)-1-acetylaspidoalbidine
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