Affiliation:
1. Department of Chemical and Biomolecular Engineering National University of Singapore Singapore 117585 Singapore
2. School of Chemistry and Chemical Engineering Beijing Institute of Technology Beijing 100081 (P. R. China
3. Department of Electrical and Computer Engineering National University of Singapore Singapore 117576 Singapore
4. Department of Chemistry and Nanoscience Ewha Womans University 52 Ewhayeodae-gil, Seodaemun-gu Seoul 03760 (Republic of Korea
Abstract
AbstractSingle‐atom catalysts manifest nearly 100 % atom utilization efficiency, well‐defined active sites, and high selectivity. However, their practical applications are hindered by a low atom loading density, uncontrollable location, and ambiguous interaction with the support, thereby posing challenges to maximizing their electrocatalytic performance. To address these limitations, the ability to arrange randomly dispersed single atoms into locally ordered single‐atom catalysts (LO‐SACs) substantially influences the electronic effect between reactive sites and the support, the synergistic interaction among neighboring single atoms, the bonding energy of intermediates with reactive sites and the complexity of the mechanism. As such, it dramatically promotes reaction kinetics, reduces the energy barrier of the reaction, improves the performance of the catalyst and simplifies the reaction mechanism. In this review, firstly, we introduce a variety of compelling characteristics of LO‐SACs as electrocatalysts. Subsequently, the synthetic strategies, characterization methods and applications of LO‐SACs in electrocatalysis are discussed. Finally, the future opportunities and challenges are elaborated to encourage further exploration in this rapidly evolving field.