Affiliation:
1. Department of Chemistry and State Key Laboratory of Synthetic Chemistry The University of Hong Kong Pokfulam Road Hong Kong P. R. China
2. Institute of Organic Chemistry Ulm University Albert-Einstein-Allee 11 89081 Ulm Germany
Abstract
AbstractBoth pillar[n]arenes (P[n]As) and [n]cycloparaphenylenes ([n]CPPs) play an important role in supramolecular chemistry. Herein, we report the precise synthesis of two multifunctional bismacrocycles [n]CPP‐P[5]A by integrating P[5]A into the [n]CPP backbone. The photoluminescence quantum yield (ΦF) of the bismacrocycles was found to show a dramatic increase relative to the corresponding [n]CPPs. The chiral enantiomers (pR)/(pS)‐[8]CPP‐P[5]A were successfully isolated by chiral HPLC, and showed promising properties of circularly polarized luminescence (glum≈0.02). In addition, [n]CPP‐P[5]A bismacrocycles are capable of binding pyridinium salts and fullerene derivatives with high affinity and specificity within the two distinct cavities. Transient absorption studies showed that photo‐induced electron transfer occurs in [10]CPP‐P[5]A⊃C60 complex. Our results suggest that [n]CPP‐P[5]A are potentially useful in CPL‐active materials, multiple guest recognition and supramolecular polymer preparation.
Funder
CAS-Croucher Funding Scheme for Joint Laboratories
Innovation and Technology Commission
Cited by
2 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献