Synthesis of Long‐Chain Polyamides via Main‐Chain Modification of Polyethyleneketones-Reference-Cited by-同舟云学术

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Synthesis of Long‐Chain Polyamides via Main‐Chain Modification of Polyethyleneketones

Published:2024-09-05 Issue: Volume: Page:
ISSN:0044-8249
Container-title:Angewandte Chemie
language:en
Short-container-title:Angewandte Chemie

Author:

Lu Yipu¹^ORCID,Takahashi Kohei¹^ORCID,Zhou Jian²,Nontarin Roopsung²,Nakagawa Shintaro²^ORCID,Yoshie Naoko²^ORCID,Nozaki Kyoko¹^ORCID

Affiliation:

1. Department of Chemistry and Biotechnology Graduate School of Engineering The University of Tokyo 7-3-1 Hongo Bunkyo-ku Tokyo 113-8656 Japan

2. Institute of Industrial Science The University of Tokyo 4-6-1 Komaba Meguro-ku Tokyo 153-8505 Japan

Abstract

AbstractLong‐chain polyamides (polyethyleneamides) were prepared from polyethylenes bearing in‐chain carbonyl groups (polyethyleneketones) by the oxime formation and successive Beckmann rearrangement. (Diethylamino)sulfur trifluoride (DAST) was utilized as a promoter, which allowed mild conversion of the oxime group in spite of low solubility of the polymers. The polyethyleneamide exhibited different tensile property compared to a commercial HDPE.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ange.202410849

Reference39 articles.

1. Postpolymerization Modification: A Powerful Tool for the Synthesis and Function Tuning of Stimuli‐Responsive Polymers

2. Synthesis of Functional Polymers by Post-Polymerization Modification

3. Architecture-transformable polymers: Reshaping the future of stimuli-responsive polymers

4. C−H Functionalization of Commodity Polymers

5. Advancing the Logic of Polymer Synthesis via Skeletal Rearrangements

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