A Phosphine‐Amine‐Linked Covalent Organic Framework with Staggered Stacking Structure for Lithium‐Ion Conduction

Author:

Tan Jing1,Weng Weijun1,Zhu Jinyao1,Liu Shujing1,Xu Jie2,An Shuhao3,Wang Changchun1,Guo Jia1ORCID

Affiliation:

1. State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science Fudan University 200438 Shanghai China

2. Department of Chemistry Fudan University 200438 Shanghai China

3. School of Chemistry and Molecular Engineering East China University of Science and Technology 200237 Shanghai China

Abstract

AbstractIn‐plane ionic conduction over two‐dimensional (2D) materials is desirable for flexible electronics. Exfoliating 2D covalent organic frameworks (COFs) towards a few layers is highly anticipated, whereas most examples remain robust via π‐stacking against the interlayered dislocation. Herein, we synthesize a phosphine‐amine‐linked 2D COF by a nucleophilic substitution reaction of phosphazene with amines. The synthesized COF is crystalline, and stacks in an AB‐staggered fashion, wherein the AB dual layers are interlocked by embedding P−Cl bonds from one to another layer, and the non‐interlocked layers are readily delaminated. Therefore, in situ post‐quaternization over phosphazene can improve the ionization of backbones, accompanied by layered exfoliation. The ultrathin nanosheets can decouple lithium salts for fast solid‐state ion transport, achieving a high conductivity and low activation energy. Our findings explore the P−N substitution reaction for COF crystallization and demonstrate that the staggered stacking 2D COFs are readily exfoliated for designing solid electrolytes.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Medicine

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