Recent Advances in Dearomative Partial Reduction of Benzenoid Arenes

Author:

Liu De‐Hai1,Ma Jiajia1ORCID

Affiliation:

1. Frontiers Science Center for Transformative Molecules Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs School of Chemistry and Chemical Engineering and Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University Shanghai 200240 P. R. China

Abstract

AbstractDearomative partial reduction is an extraordinary approach for transforming benzenoid arenes and has been well‐known for many decades, as exemplified by the dehydrogenation of Birch reduction and the hydroarylation of Crich addition. Despite its remarkable importance in synthesis, this field has experienced slow progress over the last half‐century. However, a revival has been observed with the recent introduction of electrochemical and photochemical methods. In this Minireview, we summarize the recent advancements in dearomative partial reduction of benzenoid arenes, including dihydrogenation, hydroalkylation, arylation, alkenylation, amination, borylation and others. Further, the intriguing utilization of dearomative partial reduction in the synthesis of natural products is also emphasized. It is anticipated that this Minireview will stimulate further progress in arene dearomative transformations.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Fundamental Research Funds for Central Universities of the Central South University

Publisher

Wiley

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