Affiliation:
1. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience National Center for Nanoscience and Technology Beijing 100190 P. R. China
2. University of Chinese Academy of Sciences Beijing 100049 P. R. China
3. Hefei Institute of Physical Science Chinese Academy of Sciences Hefei 230031 P. R. China
Abstract
AbstractPhotoelectrochemistry (PEC) is burgeoning as an innovative solution to organic synthesis. However, the current PEC systems suffer from limited reaction types and unsatisfactory performances. Herein, we employ efficient BiVO4 photoanodes with tailored deposition layers for customizing two PEC approaches toward C−N and C−P bond formation. Our process proceeds under mild reaction conditions, deploying easily available substrates and ultra‐low potentials. Beyond photocatalysis and electrocatalysis, customized PEC offers high efficiency, good functional group tolerance, and substantial applicability for decorating drug molecules, highlighting its promising potential to enrich the synthetic toolbox for broader organic chemistry of practical applications.