Affiliation:
1. School of Materials Science and Engineering, Key Lab of Guangdong Province for High Property and Functional Polymer Materials South China University of Technology Guangzhou China
2. Research and Development Center Guangdong Dymatic Chemicals Group Co., Ltd Foshan China
Abstract
AbstractWith the increasing deterioration of environmental and ecology caused by industrial wastewater pollution and petroleum spill accidents, superhydrophobic materials for oil–water separation have attracted considerable attention. Herein, we propose a facile approach to fabricate fluorine‐free superhydrophobic cotton fabric (CF) for oil–water separation after the coverage of chitosan (CS) and titanium dioxide (TiO2) nanoparticles and the subsequent hydrophobization modification by hexadecyltrimethoxysilane (HDTMS). The obtained HDTMS‐TiO2/CS@CF showed superhydrophobicity with a high water contact angle of 160.6° as well as excellent self‐cleaning capability, non‐adhesion capability and surface stability. Moreover, the CF was successfully applied for the separation of various oil–water mixtures. The separation efficiency for trichloromethane‐water mixture reached 95.8%, and still maintained 95.6% after 30 separation cycles. In addition, the CF also possessed superior photocatalytic degradation capability for organic contaminant such as oil red O and the degradation rate was 86.2% under UV irradiation for 180 min. The preparation method in this work is simple, environmentally friendly, low‐cost, and easy to produce on a large scale. The findings conceivably stand out as a new method to fabricate superhydrophobic materials and show great application potential in the fields of oil–water separation and water purification.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Guangdong Province
Subject
Materials Chemistry,Polymers and Plastics,Surfaces, Coatings and Films,General Chemistry